DMSE alum’s green hydrogen innovation for clean energy

DMSE alum and fall 2023 Wulff Lecture speaker Sossina Haile uses ammonia and a “superprotonic” material for efficient and eco-friendly energy generation.

Renewable energy today—mainly derived from the sun or wind—depends on batteries for storage. While costs have dropped in recent years, the pursuit of more efficient means of storing renewable power continues.
“All of these technologies, unfortunately, have a long way to go,” said Sossina Haile SB ’86, PhD ’92, the Walter P. Murphy Professor of Materials Science and Engineering at Northwestern University, on September 28 at MIT. She was the speaker of the fall 2023 Wulff Lecture, an event hosted by the Department of Materials Science and Engineering (DMSE) to ignite enthusiasm for the discipline.
To add to the renewable energy mix—and help quicken the pace to a sustainable future—Haile is working on an approach based on hydrogen in fuel cells, particularly for eco-friendly fuel in cars. Fuel cells, like batteries, produce electricity from chemical reactions but don’t lose their charge so long as fuel is supplied.
To generate power, the hydrogen must be pure—not attached to another molecule. Most methods of producing hydrogen today require burning fossil fuel, which generates planet-heating carbon emissions. Haile proposes a “green” process using renewable electricity to extract the hydrogen from steam.
When you use hydrogen in a fuel cell, “you have water as the product, and that’s the beautiful zero emissions,” Haile said, referring to the renewable energy production cycle that is set in motion.

Northwestern University’s Sossina Haile explores the potential of using ammonia as a carrier for hydrogen in fuel cells, emphasizing its advantages in energy storage.

Ammonia fuels hydrogen’s potential

Hydrogen is not yet widely used as a fuel because it’s difficult to transport. For one, it has low energy density, meaning a large volume of hydrogen gas is needed to store a usable amount of energy. And storing it is challenging because hydrogen’s tiny molecules can infiltrate metal tanks or pipes, causing cracks and gas leakage.
Haile’s solution for transporting hydrogen is using ammonia to “carry” it. Ammonia is three parts hydrogen and one part nitrogen, so the hydrogen needs to be separated from the nitrogen before it can be used in the kind of fuel cells that can power cars.
Ammonia has some advantages, including existing pipelines and a high transmission capacity, Haile said—so more power can be transmitted at any given time.
To extract the hydrogen from ammonia, Haile has built devices that look a lot like fuel cells, with cesium dihydrogen phosphate as an electrolyte. The “superprotonic” material displays high proton conductivity—it allows protons, or positively charged particles, to move through it. This is important for hydrogen, which has just a proton and an electron. By letting only protons through the electrolyte, the device strips hydrogen from the ammonia, leaving behind the nitrogen.
The material has other benefits, too, Haile said: “It’s inexpensive, nontoxic, earth-abundant—all these good things that you want to have when you think about a sustainable energy technology.”

Sparking interest—and hope

Haile’s talk piqued interest in the audience, which nearly filled the 6-120 auditorium at MIT, which seats about 150 people.
Nikhita Law, a sophomore in DMSE with an interest in climate change studies, heard hope in Haile’s talk for a more sustainable future.
“A major problem in making our energy system sustainable is finding ways to store energy from renewables,” Law said. Even if hydrogen-powered cars are not as widescale as lithium-battery-powered electric cars, “a permanent energy storage station where we convert electricity into hydrogen and convert it back seems like it makes more sense than mining more lithium.”
Another attendee, Daniel Tong, a senior in DMSE, learned about the challenges involved in transporting hydrogen at another seminar and was curious to learn more. “This was something I hadn’t thought of: can you carry hydrogen more effectively in a different form? That’s really cool.”
He added that seminars and talks like the Wulff Lecture are helpful in keeping people up-to-date in a wide-ranging, interdisciplinary field such as materials science and engineering, which spans chemistry, physics, engineering, and other disciplines. “This is a really good way to get exposed to different parts of materials science. There are so many more facets than you know of.”
In her talk, Haile encouraged audience members to get involved in sustainability research. “There’s lots of room for further insight and materials discovery,” she said.
Haile concluded by underscoring the challenges faced by developing countries in dealing with climate change impacts, particularly those near the equator where there isn’t adequate infrastructure to deal with shifts such as big swings in precipitation and temperature. For the people who aren’t driven to solve problems that affect people on the other side of the world, Haile offered some additional motivation.
“I’m sure many of you enjoy coffee. This is going to put the coffee crops in jeopardy as well,” she said.